Unless I'm mistaken it sounds like you have Sky and pay for TNT sports directly with Discovery and not via Sky.
If so you can't use Sky Go to watch the live TNT Sporte channels. What I also suspect has happened is that you have 2 Discovery + accounts ( one you have linked with your Sky account and one that comes as part of subscribing directly with TNt Sports). In this scenario having the 2 discovery + accounts would be normal as the Sky one would give access to discovery + Standard and the one you get for subscribing directly to TNT sports would give you a Discovery + Premoum tier account which has the access to TNT Sports.
This scenario would certainly explained the information provided so far in this thread.
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