@Megandchip
If you don't have the options posted by @mike+simmonds above you would need to rent it again via your Sky TV equipment to watch it via that if you are a Sky TV customer. As you would be charged again you might want to get in touch with Sky Store support about the rental via the phone app to see if they can cancel it for you.
They have a live chat you can use that is available from 11am-7.30pm Monday to Saturday and can be found here:
https://www.skystore.com/help/contact-us
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