You can do that here:
https://www.sky.com/shop/mobile
Make sure you are logged into your Sky mobile account and that you don't order a data plan if you want to use the sim you have in your new phone. Should you be sent a sim don't activate it or you will be paying for a second one.
You will be credit checked when placing the order so should you be sent a order cancelled one at anytime this will be due to a failed credit check.
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